沸石轉(zhuǎn)輪濃縮VOCs凈化技術(shù)是利用沸石分子篩吸附劑對(duì)排放廢氣中的VOCs進(jìn)行吸附凈化的技術(shù)。沸石分子篩是結(jié)晶硅鋁酸鹽，以其規(guī)整的晶體結(jié)構(gòu)、均勻一致的孔分布和可調(diào)變的表面性質(zhì)在VOCs廢氣治理領(lǐng)域得到廣泛應(yīng)用。沸石轉(zhuǎn)輪是大多數(shù)涂裝企業(yè)在治理VOCs過程中必不可少的系統(tǒng)部件，主要用于大風(fēng)量低濃度的VOCs廢氣富集。

The zeolite rotary wheel concentration VOCs purification technology is a technology that uses zeolite molecular sieve adsorbents to adsorb and purify VOCs in exhaust gas emissions. Zeolite molecular sieve is a crystalline aluminosilicate, widely used in the field of VOCs waste gas treatment due to its regular crystal structure, uniform pore distribution, and adjustable surface properties. Zeolite wheel is an essential system component in the treatment of VOCs in most coating enterprises, mainly used for the enrichment of high air volume and low concentration VOCs waste gas.

一、沸石轉(zhuǎn)輪的工作原理

1、 The working principle of zeolite wheel

眾所周知，沸石轉(zhuǎn)輪面在物理區(qū)間被分為吸附區(qū)、脫附區(qū)、冷卻區(qū)域，各區(qū)域比例為10:1:1，分區(qū)圖下圖所示：

As is well known, the zeolite wheel surface is divided into adsorption zone, desorption zone, and cooling zone in the physical range, with a ratio of 10:1:1 for each zone. The zoning diagram is shown in the following figure:

大風(fēng)量低濃度的VOCs經(jīng)過沸石轉(zhuǎn)輪后，由于分子之間的范德華力，VOCs被沸石微孔所吸附，凈化后的氣體可直接排至排氣筒。被吸附在沸石轉(zhuǎn)輪上的有機(jī)物再通過一小股180℃～200℃的溫度的氣體進(jìn)行脫附。脫附出來的高濃度廢氣再送入其他設(shè)備進(jìn)行處理，從而降低了末端處理設(shè)備的負(fù)荷，降低了運(yùn)行能耗，被廣泛使用在噴涂行業(yè)、包裝行業(yè)、電子半導(dǎo)體行業(yè)。

After the high air volume and low concentration VOCs pass through the zeolite impeller, due to the van der Waals forces between molecules, VOCs are adsorbed by the zeolite micropores, and the purified gas can be directly discharged into the exhaust pipe. The organic matter adsorbed on the zeolite wheel is then desorbed through a small stream of gas at a temperature of 180 ℃ to 200 ℃. The high concentration waste gas desorbed is sent to other equipment for treatment, thereby reducing the load of the end treatment equipment and reducing operational energy consumption. It is widely used in the spray coating industry, packaging industry, and electronic semiconductor industry.

二、吸附脫附性能及改善措施

2、 Adsorption and desorption performance and improvement measures

轉(zhuǎn)輪按設(shè)定的速度轉(zhuǎn)動(dòng)，實(shí)現(xiàn)了廢氣的循環(huán)吸附脫附。然而對(duì)于廢氣成分復(fù)雜，含有高沸點(diǎn)的有機(jī)物，往往180℃-200℃的溫度不足以將有機(jī)物脫附出來，這些高沸點(diǎn)有機(jī)物殘留在沸石的孔隙中，隨著時(shí)間的推移，殘留的累積量越來越多，可用于吸脫附的孔隙越來越少，終導(dǎo)致轉(zhuǎn)輪出口有機(jī)物濃度偏高，排放不達(dá)標(biāo)現(xiàn)象。因此，必須采取一定的措施，將高沸點(diǎn)組分從沸石中脫附出來，恢復(fù)轉(zhuǎn)輪的吸附容量。

The wheel rotates at the set speed to achieve the cyclic adsorption and desorption of waste gas. However, for exhaust gases with complex components and high boiling point organic compounds, temperatures between 180 ℃ and 200 ℃ are often insufficient to desorb the organic compounds. These high boiling point organic compounds remain in the pores of zeolites, and over time, the accumulated amount of residues increases. The number of pores available for adsorption and desorption decreases, ultimately leading to a high concentration of organic compounds at the outlet of the impeller and substandard emissions. Therefore, certain measures must be taken to desorb high boiling components from the zeolite and restore the adsorption capacity of the impeller.

無論是哪種沸石轉(zhuǎn)輪，廠商一般會(huì)建議周期性對(duì)轉(zhuǎn)輪進(jìn)行高溫再生。如：將脫附溫度設(shè)定為300℃，進(jìn)行高溫再生。然而，高溫再生時(shí)轉(zhuǎn)輪處在一個(gè)高溫、高濃度的環(huán)境中，安全風(fēng)險(xiǎn)級(jí)別也非常高。常規(guī)做法是配備專業(yè)技術(shù)人員至現(xiàn)場(chǎng)操作、監(jiān)控高溫再生過程，并根據(jù)轉(zhuǎn)輪及系統(tǒng)相關(guān)實(shí)際運(yùn)行數(shù)據(jù)以及實(shí)踐經(jīng)驗(yàn)，實(shí)時(shí)手動(dòng)調(diào)整運(yùn)行參數(shù)或采取應(yīng)急措施。顯然，這樣的操作，效率低下，對(duì)專業(yè)技術(shù)人員的依賴程度較高。因此，將沸石濃縮轉(zhuǎn)輪手動(dòng)高溫再生操作，轉(zhuǎn)換成自動(dòng)程序控制，顯得尤為迫切。

Regardless of the type of zeolite impeller, manufacturers generally recommend periodic high-temperature regeneration of the impeller. For example, set the desorption temperature to 300 ℃ for high-temperature regeneration. However, during high-temperature regeneration, the impeller is in a high-temperature, high concentration environment, and the safety risk level is also very high. The conventional approach is to equip professional technical personnel to operate and monitor the high-temperature regeneration process on site, and manually adjust operating parameters or take emergency measures in real time based on the actual operating data and practical experience of the impeller and system. Obviously, such operations are inefficient and rely heavily on professional technicians. Therefore, it is particularly urgent to convert the manual high-temperature regeneration operation of the zeolite concentration wheel into automatic program control.

三、高溫?zé)崦摳娇刂七壿嬙O(shè)計(jì)

3、 Design of High Temperature Thermal Desorption Control Logic

轉(zhuǎn)輪高溫?zé)崦摳椒謨煞N模式，分別為“在線式”和“離線式”。

There are two modes for high-temperature desorption of the impeller, namely "online" and "offline".

“離線式”：高溫再生時(shí)，轉(zhuǎn)輪停止轉(zhuǎn)動(dòng)，脫附入口溫度從200℃按一定的梯度逐步升溫至300℃。高溫脫附結(jié)束后，將轉(zhuǎn)輪再生干凈的區(qū)域轉(zhuǎn)至冷卻區(qū)，同時(shí)將含有高沸點(diǎn)的待脫附區(qū)域轉(zhuǎn)入脫附區(qū)。根據(jù)以上原則，并結(jié)合轉(zhuǎn)輪分區(qū)10:1:1的特點(diǎn)，可計(jì)算出轉(zhuǎn)輪待高溫再生區(qū)域送入轉(zhuǎn)輪再生區(qū)域所要的運(yùn)轉(zhuǎn)時(shí)間。如：假設(shè)轉(zhuǎn)輪50HZ運(yùn)行，轉(zhuǎn)1圈需要15min,因此從吸附區(qū)轉(zhuǎn)至脫附區(qū)，轉(zhuǎn)輪轉(zhuǎn)動(dòng)1次理論所需要的時(shí)間為：15min/(10+1+1)×60s/min=75s。但為保證各區(qū)域均能完全高溫再生，轉(zhuǎn)輪相鄰兩次高溫再生面足夠的搭接長(zhǎng)度，同時(shí)兼顧轉(zhuǎn)輪脫附區(qū)隔板保溫厚度的影響，選取轉(zhuǎn)輪每次連續(xù)轉(zhuǎn)動(dòng)時(shí)間為60s，此處稱為步長(zhǎng)為60s。

Offline mode: During high-temperature regeneration, the rotor stops rotating and the desorption inlet temperature gradually increases from 200 ℃ to 300 ℃ in a certain gradient. After the high-temperature desorption is completed, transfer the clean area regenerated by the impeller to the cooling zone, and at the same time, transfer the area containing high boiling points to the desorption zone. Based on the above principles and combined with the characteristics of the 10:1:1 partition of the impeller, the operating time required for the impeller to be sent into the high-temperature regeneration area can be calculated. For example, assuming the wheel runs at 50HZ and takes 15 minutes to complete one revolution, the theoretical time required for the wheel to rotate once from the adsorption zone to the desorption zone is: 15 minutes/(10+1+1) × 60s/min=75s. However, in order to ensure complete high-temperature regeneration in all areas, there is sufficient overlap length between the two adjacent high-temperature regeneration surfaces of the impeller, while taking into account the influence of the insulation thickness of the separator in the detachment zone of the impeller, a continuous rotation time of 60 seconds is selected for each rotation of the impeller, which is referred to as a step length of 60 seconds.